I need to clarify that you won't wreck anything if you put both ends wrong. So if you think "thick wires long edge" (which is the opposite of what I said) and do that on both sides, you'll live to tell the tale. If you just guess and do one end right and the other wrong, you'll risk letting the magic smoke out of something.
But yeah, the power side is always the thick side - but there's no guarantee anything will be thicker. Some harnesses are, some aren't. It looks like yours has one thick wire to two power pins, on your connector, and there's no -5V.
If your board doesn't have a key on pin 7, (either a missing pin or a physical block of some kind) then look at the circuits on that board - they'll usually be joined together, or thicker, or grouped together in some way, on the power end. On the opposite end, the last two pins on both sides are ground, so they'll often look different too - but only two pins instead of six.
Also, usually, there'll only be a via (a small pipe that connects one side of the board to the other) connecting both sides of the power pins: ground, +5V, -5V, 12V. None of the other pins will do this, as a rule. Of course on a CPS2 you can't see the board, but this would help with anything that's not in a case.